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The engine-out (EO) total and speciated hydrocarbon emissions data from the Auto-Oil Program Phase II Heavy Hydrocarbon Study had been analyzed. The methodology was to first investigate the stabilized EO emissions (Bag 2) of a specific vehicle (Vehicle 04B, a 1989 Model Year Ford Taurus); then the vehicle-to-vehicle differences in Bag2 emissions were considered. Finally, the differences in the Bag2 and the starting/warm-up EO emissions (Bag1) were examined. The speciated emissions may be interpreted as a “feed-through” part due to the unreacted fuel species, and an “offset” part due to the decomposition products. The significant non-fuel emitted species were methane and the olefins. The HC emissions for vehicles with different total emissions were similar in species composition. For both the total and speciated emissions, there was no substantial difference between the Bag1 and Bag2 values for Vehicle 04B.

A method for determining the flame contour based on the flame arrival time at the fiber optic (FO) spark plug and at the head gasket ionization probe (IP) locations has been developed. The experimental data were generated in a single-cylinder Ricardo Hydra spark-ignition engine. The head gasket IP, constructed from a double-sided copper-clad circuit board, detects the flame arrival time at eight equally spaced locations at the top of the cylinder liner. Three other IP's were also installed in the cylinder head to provide additional intermediate data on flame location and arrival time. The FO spark plug consists of a standard spark plug with eight symmetrically spaced optical fibers located in the ground casing of the plug. The cylinder pressure was recorded simultaneously with the eleven IP signals and the eight optical signals using a high-speed PC-based data acquisition system.

A fuel volatility model based on the major species present in the fuel has been formulated. The model accurately predicts the ASTM distillation curves and Reid Vapor Pressure for hydrocarbon fuels. The model may be used to assess the fuel effects on the extent of evaporation and the vapor composition in the mixture preparation process.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

The effects of fuel volatility and degree of enrichment on the starting and warm-up behavior of a modern four-valve spark ignition engine with port-fuel-injection were studied. Quantities of interest are the number of cycles to reach first significant firing, the time scale (τr) for the IMEP development, the decay rate of the IMEP fluctuation, and the RMS fluctuation after 3τr. A selected matrix of fuels that included various volume ratios of indolene/MTBE and iso-octane/n-pentane was used. The amount of fuel injected per cycle was varied from stoichiometric to a fuel equivalence ratio of 1.5. The engine behavior (as quantified by the quantities described in the above) is found to correlate well to a single parameter - the fuel equivalence ratio based on the fuel vapor mass calculated from an isothermal equilibrium flash vaporization of the fuel in the vapor boundary layer of the intake flow at intake manifold temperature.

A reciprocating test apparatus was constructed in which the friction of a single piston ring against a liner segment was measured. The lubrication oil film thickness was also measured simultaneously at the mid stroke of the ring travel using a laser fluorescence technique. The apparatus development and operation are described. Results are presented from a test matrix consisting of five different lubrication oils of viscosity (at 30°C) ranging from 49 to 357 cP; at three mean piston speeds of 0.45, 0.89 and 1.34 m/s; and at three ring normal loading of 1.4, 2.9 and 5.7 MPa. At mid stroke, the oil film thickness under the ring was ∼0.5 to 4 μm; the frictional coefficient was ∼0.02 to 0.1. The frictional coefficient for all the lubricants tested increased with normal load, and decreased with piston velocity. Both mixed and hydrodynamic lubrication regimes were observed. The friction behaviors were consistent with the Stribeck diagram.

The fuel injection process in the port of a firing 4-valve SI engine at part load and 25°C head temperature was observed by a high speed video camera. Fuel was injected when the valve was closed. The reverse blow-down flow when the intake valve opens has been identified as an important factor in the mixture preparation process because it not only alters the thermal environment of the intake port, but also strip-atomizes the liquid film at the vicinity of the intake valve and carries the droplets away from the engine. In a series of “fuel-on” experiments, the fuel injected in the current cycle was observed to influence the fuel delivery to the engine in the subsequent cycles.

A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.

The fuel effects on throttle transients in PFI spark ignition engines were assessed through experiments with simultaneous step change of the throttle position from part load to WOT and increment of the injected fuel amount. The test matrix consisted of various gasoline/methanol blends from pure gasoline to pure methanol, coolant temperatures at 40C (for cold engine condition) and 80C (for warm engine), and different levels of fuel enrichment at the WOT condition. The x-τ model was used to interpret the engine GIMEP response in the transient. Using the model, a procedure was developed to calculate the parameters of the transient from the data. These parameters were systematically regressed against the fuel distillation points, the increment in injected fuel mass in the transient, and the enthalpy required to evaporate the fuel increment as the explanatory variables.

The heat transfer characteristics of impinging diesel sprays were studied in a Rapid Compression Machine. The temporal and spatial distributions of the heat transfer around the impingement point -were measured by an array of high frequency response surface thermocouples. Simultaneously, the flow field of the combusting spray was photographed with high speed movie through the transparent head of the apparatus. The results for the auto-ignited fuel sprays were compared to those of non-combusting sprays which were carried out in nitrogen. The values of the heat flux from the combusting sprays were found to be substantially different from those of the non-combusting sprays. The difference was attribute to the radiative heat transfer and the combustion generated bulk, motion and small scale turbulence.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

Throttle ramp rate effects on the in-cylinder fuel/air (F/A) excursion was studied in a production engine. The fuel delivered to the cylinder per cycle was measured in-cylinder by a Fast Response Flame Ionization detector. Intake pressure was ramped from 0.4 to 0.9 bar. Under slow ramp rates (∼1 s ramp time), the Engine Electronic Control (EEC) unit provided the correct compensation for delivering a stoichiometric mixture to the cylinder throughout the transient. At fast ramp rates (a fraction of a second ramps), a lean spike followed by a rich one were observed. Based on the actual fuel injected in each cycle during the transient, a x-τ model using a single set of x and τ values reproduced the cycle-to-cycle in-cylinder F/A response for all the throttle ramp rates.

An adaptive air/fuel ratio controller for SI engine throttle transient was developed. The scheme is based on an event- based, single- parameter fuel dynamics model. A least- square- error algorithm with an active forgetting factor was used for parameter identifications. A one- step- look- ahead controller was designed to maintain the desired air/fuel ratio by canceling the fuel dynamics with the controller setting updated adaptively according to the identified parameters. When implemented on a Ford Ztech engine and tested under a set of throttle- transient operations, the adaptive controller learned quickly and performed well.

The spark ignition engine particulate number (PN) emissions have been correlated to a particulate matter index (PMI) in the literature. The PMI value addresses the fuel effect on PN emission through the individual fuel species reactivity and vapor pressure. The latter quantity is used to account for the propensity of the non-volatile fuel components to survive to the later part of the combustion event as wall liquid films, which serve as sources for particulate emission. The PMI, however, does not encompass the suppression of vaporization by the evaporative cooling of fuel components, such as ethanol, that have high latent heat of vaporization. This paper assesses this evaporative cooling effect on PN emissions by measurements in a GDI engine operating with a base gasoline which does not contain oxygenate, with a blend of the gasoline and ethanol, and with a blend of the gasoline, ethanol, and a hydrocarbon additive so that the blend has the same PMI as the original gasoline.

The purpose of this work was to develop an understanding of how liquid fuel transported into the cylinder of a port-fuel-injected gasoline-fueled SI engine contributes to hydrocarbon (HC) emissions. To simulate the liquid fuel flow from the valve seat region into the cylinder, a specially designed fuel probe was developed and used to inject controlled amounts of liquid fuel onto the port wall close to the valve seat. By operating the engine on pre-vaporized Indolene, and injecting a small amount of liquid fuel close to the valve seat while the intake valve was open, we examined the effects of liquid fuel entering the cylinder at different circumferential locations around the valve seat. Similar experiments were also carried out with closed valve injection of liquid fuel at the valve seat to assess the effects of residual blowback, and of evaporation from the intake valve and port surfaces.

The liquid fuel entry into the cylinder and its subsequent behavior through the combustion cycle were observed by a high speed CCD camera in a transparent engine. The videos were taken with the engine firing under cold conditions in a simulated start-up process, at 1,000 RPM and intake manifold pressure of 0.5 bar. The variables examined were the injector geometry, injector type (normal and air-assisted), injection timing (open- and closed-valve injection), and injected air-to-fuel ratios. The visualization results show several important and unexpected features of the in-cylinder fuel behavior: 1) strip-atomization of the fuel film by the intake flow; 2) squeezing of fuel film between the intake valve and valve seat at valve closing to form large droplets; 3)deposition of liquid fuel as films distributed on the intake valve and head region. Some of the liquid fuel survives combustion into the next cycle.

The NOx emissions during the crank-start and cold fast-idle phases of a GDI engine are analyzed in detail. The NOx emissions of the first 3 firing cycles are studied under a wide set of parameters including the mass of fuel injected, start of injection, and ignition timing. The results show a strong dependence of the NOx emissions with injection timing; they are significantly reduced as the mixture is stratified. The impact of different valve timings on crank-start NOx emissions was analyzed. Late intake and early exhaust timings show similar potential for NOx reduction; 26-30% lower than the baseline. The combined strategy, resulting in a large symmetric negative valve overlap, shows the greatest reduction; 59% lower than the baseline. The cold fast-idle NOx emissions were studied under different equivalence ratios, injection strategies, combustion phasing, and valve timings. Slightly lean air-fuel mixtures result in a significant reduction of NOx.

In a previous study, a wide range of gasolines with RON∼90 were tested in a single cylinder engine operated in HCCI mode using negative valve overlap, and all were found to have very similar behavior near the low-load limit. Here we broaden the range of gasolines to include PRF90 and PRF60. At high engine speed, both PRF60 and PRF90 behave similarly to all the other gasolines tested. However, at 1000 RPM, PRF90 is very different from all the other gasolines: it ignites very late, and the engine cannot be operated at low load. Simulations using a popular fuel chemistry model cannot distinguish PRF60 and PRF90 under these conditions. However, a new fuel chemistry model correctly shows the onset of fuel sensitivity at low engine speed. Sensitivity analyses indicate the low-load limit at low engine speed strongly depend on both the chemistry parameters and on the heat-transfer parameters.

A model for calculating the residual gas fraction in spark ignition engines has been formulated. The model accounts explicitly for the contribution due to the back flow of exhaust gas to the cylinder during the valve overlap period. The model has been calibrated with in-cylinder hydrocarbon measurements at different values of intake pressure, engine speed, and valve overlap timings.